| Source |
: |
Mineral Kingdom |
| Formula |
: |
AS2O3 |
| Synonym |
: |
English, Arsenious acid; French, acide arsenieux Arsenic blanc;
German, Arseige Saure |
| Description |
: |
A white or transparent amorphous lumps or crystalline powder,
odourless, stable in air. Poison! It is slowly soluble in water.
The amorphous variety being more soluble than the crystalline variety.It
is sparingly soluble in alcohol. It’s completely soluble in
glycerin.It may be obtained by roasting certain arsenical ores.
Arsenic trioxide, dried at 105 degree for two hours contains not
less than 99.8 percent of AS2O3. |
| Identification |
: |
(i) Sublimes on heating, with the formation of transparent octahedral
crystals.
(ii) A small quantity warmed with about 5ml of hydrochloric acid,
gives a brown colored or white precipitate on addition of few drops
of Solution of stannous chloride.
(iii) An acidified solution gives a yellow precipitate with hydrogen
Sulphide. |
| Non-Volatile matter |
: |
Leaves not more than 0.1 percent of the residue. |
| Assay |
: |
Dissolve about 0.1g accurately weighed in about 20ml of boiling
water and 5 ml of 0.1N sodium hydroxide cool; add 5ml of 1 hydrochloric
acid followed, by about 3 g of sodium bicarbonate, and triturate
the mixture with 0.1 N iodine using starch as indicator. Each ml
of 0.1 N iodine is equivalent to 0.004946 g of AS2O3. |
| History & Authority |
: |
Allen’s Encyclopedia,Mat.Med.Vol 1 496. |
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| Preparation: |
|
(a) Solution Drug
Strength (1/100) Arsenicum
Album in fine powder 10g
Glycerin 100ml
Strong Alcohol
100ml Purified water in sufficient
quantity To make one thousand milliliters of mother solution.
Heat fine powder of Arsenicum Album
with glycerin at 100 degree until a clear solution is obtained.
Cool this solution and add it to 750 ml of purified water and 100ml
of strong alcohol. Mix well. Bring the volume to one thousand milliliters
by adding purified water if found necessary.
(b) Potency: 3x and higher with dispensing alcohol.
(c) Trituration 1 c Drug Strength 1/100
Arsenicum Album in fine powder 10g
Saccharum Lactis 990g
To make one thousand grams of the trituration.
(d) Potency: 3x and higher to be triturated, 6x may be converted
to liquid 8x, 9x and higher with dispensing alcohol.. |
| Caution |
: |
Not to be prescribed below 3x. |